Heavy metal and clay mineral analyses in the sediments of Upper Gulf of Thailand and their implications on sedimentary provenance and dispersion pattern

Abstract

Forty-eight sediment samples collected in the Upper Gulf of Thailand (UGOT) and its nearby rivers including the Mae Klong, Tha Chin, Chao Phraya, and Bang Pakong were analyzed for grain size, heavy metals (Cu, Pb, Zn, Cr, and Cd), and clay minerals. The results reveal that fine-grained sediments with Mz<30μm concentrate in the northern coastal area and coarse-grained fractions increase in a seaward direction. The grain size of the sediments mainly controls heavy metal concentrations. The concentrations of Cu, Pb, Zn, and Cr are higher in the northern part of UGOT, with ranges above 20, 23, 45, and 50mgkg−1, than in other sampling areas. Meanwhile, Cd content is greater than 120μgkg−1 in sediments near the Bang Pakong River mouth and area between the Tha Chin and Mae Klong rivers mouth. The concentrations of heavy metals are higher than background data, and statistical analysis of geo-accumulation index indicates that the study area is either unpolluted to moderately polluted or moderately polluted by heavy metals. Our results also verify that illite is the dominant clay mineral, followed by kaolinite, chlorite, and smectite in terms of semi-quantitative content. Smectite/kaolinite can be used as an indicator to trace the riverine sediment in the study area, which present a counterclockwise dispersion pattern of sediment from the Chao Phraya River.