Abstract

Heavy metal pollution, in the aquatic ecosystem, especially sediments, has become an area of concern garnering increasing attention since the past few decades. Some metals like manganese (Mn), copper (Cu), iron (Fe) and zinc (Zn) are biologically important for marine life, others like lead (Pb), cadmium (Cd), and Arsenic (As) are non-essential and become toxic at higher concentrations. These metals introduced into the marine ecosystem mainly due to anthropogenic activities. These heavy metals when discharged into the marine ecosystem may be absorbed in suspended solids, remain in seawater, etc., but ultimately end up in the sediments which act as a “sink” and later the “source”, due to their restricted mobility. Hence, monitoring the heavy metal concentrations in these marine sediments over a period of time is of great help in checking the pollution level and identifying the trend, which in turn will be instrumental in formulating sustainable practices. The paper mainly focuses on the study of the concentration of non-essential heavy metals in sea sediment around the operational areas of ONGC in western offshore area. The distribution of heavy metals in the sediments of ONGC’s exploratory blocks in Mumbai High Region, Arabian Sea was investigated. Surface sediment samples collected from 5 platforms (R-12A, BLQ, NBP, ICP and NQ) of Mumbai High Region, Arabian Sea and digested samples were analyzed by ICP-MS for 75As, 111Cd and 208Pb. Comparison of results in studied 5 platforms with various sediment quality guidelines is discussed to assess the present contamination. It reveals that sediments in study area are not contaminated with respect to perceived heavy metals. Generated data will assist in future for proactive measures and minimize the impact of anthropogenic sources.

Highlights

  • Marine environmental pollution is a growing concern today

  • The sediments of the present study area were mainly composed of clay-silt (>90%) with varied proportions of clay (2952%), silt (35-49%) and sand (10-12%)

  • It is noticed that the distribution of metal concentrations in the sediments of study area has not followed particular trend as concentration varied from one location to another but variation is found minimum when area, depth, and other oceanographic parameters are concerned

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Summary

Introduction

Marine environmental pollution is a growing concern today. There are a lot of activities (both anthropogenic as well as natural) that may contribute to marine pollution, E&P activities of Oil and Gas companies being one of them. ONGC, one of the most valued Maharatnas of India, is committed to adopting sustainable E&P practices in its offshore installations, in order to protect and preserve our marine ecosystem. The study of heavy metals in the marine sediments is important in comparison to other parameters due to their non-biodegradable nature, accumulative properties and long biological half-lives. Heavy metals like lead (Pb), cadmium (Cd), and Arsenic (As) are non-essential and when discharged into the marine ecosystem may be absorbed in Corresponding author: Pramod Kumar Chemist, Environment Division, IPSHEM- ONGC Goa India

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