Heavy-impurity resonance, hybridization, and phonon spectral functions inFe1−xMxSi (M=Ir, Os)

Abstract

The vibrational behavior of heavy substitutional impurities $(M=\phantom{\rule{4.pt}{0ex}}\text{Ir},\phantom{\rule{4.pt}{0ex}}\text{Os})$ in ${\text{Fe}}_{1\ensuremath{-}x}{M}_{x}\text{Si}\phantom{\rule{4.pt}{0ex}}(x=0,0.02,0.04,0.1)$ was investigated with a combination of inelastic neutron scattering (INS), transport measurements, and first-principles simulations. Our INS measurements on single crystals mapped the four-dimensional dynamical structure factor, $S(\mathbf{Q},E)$, for several compositions and temperatures. Our results show that both Ir and Os impurities lead to the formation of a weakly dispersive resonance vibrational mode, in the energy range of the acoustic phonon dispersions of the FeSi host. We also show that Ir doping, which introduces free carriers, leads to softened interatomic force constants compared to doping with Os, which is isoelectronic to Fe. We analyze the phonon $S(\mathbf{Q},E)$ from INS through a Green's-function model incorporating the phonon self-energy based on first-principles density functional theory simulations, and we study the disorder-induced lifetimes on large supercells. Calculations of the quasiparticle spectral functions in the doped system reveal the hybridization between the resonance and the acoustic phonon modes. Our results demonstrate a strong interaction of the host acoustic dispersions with the resonance mode, likely leading to the large observed suppression in lattice thermal conductivity.