Abstract
By sequentially treating the unsaturated carbene IPr [IPr = 1,3‐bis(2,6‐diisopropylphenyl)imidazol‐2‐ylidene] with heavier alkali‐metal alkyls NaR or KR (R = CH2SiMe3) and GaR3, novel heteroleptic gallates 1 and 2 were prepared. Incorporating anionic NHC ligands, these bimetallic complexes react selectively with electrophilles to afford neutral abnormal NHC Ga complexes under mild conditions.
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