Abstract
The thermal diffusion of aqueous solutions of glucose, sucrose, ethylacetate, and 1,4-dioxan (0.1 m) contained in the pores of a sintered glass disc (or porosity G4), which is subjected to a temperature gradient, has been studied. The resulting heat of transport data have been interpreted, in terms of local changes in entropy in the solvent brought forth by the presence of the solutes, and correlated to the hydrophobic hydration effects.
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