Abstract
From differential scanning calorimetry (DSC) measurements of the decrease in the heat (enthalpy) of transition in the solid phase, the partial molar heats of solution at infinite dilution, χ, and the heats of solution or substitution, ΔHs° of I− in TlNO3 crystal, Br− and NO3− in TlI crystal along with their recovered lattice energies ΔHL° are reported. The phase diagram of the TlNO3–TlI system with details of the subsolidus region along with subsolidus region of the TlBr–TlI diagram are reported. The TlIx(NO3)1−x compositions exhibit properties, viz. structure, transition temperatures and melting temperature characteristic of a “mixed crystal” or “crystalline solid-solution” paralleling Tl(1−x)RbxNO3 behavior.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
