Heating rate effect on the thermal behavior of some clays and their blends with oil shale ash additives

Abstract

The heating rate effect on the thermal behavior of clays from Arumetsa and Kunda deposits (Estonia) and an illitic clay from Fuzerradvany (Hungary) was studied. Experiments were carried out under dynamic heating condition up to 1050 °C at the heating rates of 1.25, 2.5, 5 and 10 °C min−1 in a stream of gas mixture containing 79 % of Ar and 21 % of O2 with Setaram Labsys 1600 analyzer. Two different ashes were used as additives: the electrostatic precipitator ash from the first field and the cyclone ash formed, respectively, at circulating fluidized bed combustion (temperatures 750–830 °C) and pulverized firing (temperatures 1200–1400 °C) of Estonian oil shale at Estonian Power Plant. For calculation of kinetic parameters, the TG data were processed by the differential isoconversional Friedman method. The results of thermal analysis and the variation of the value of activation energy E along the reaction progress α indicated the complex character of decomposition of clays and their blends with Estonian oil shale ashes, and the certain differences in thermal behavior of different clays depending on their origin.