Heat discharge performance of metal hydride thermal battery under different heat transfer conditions: Experimental findings

Abstract

Thermal batteries utilizing metal hydride pairs are gaining tremendous research appeal for their applications in thermochemical energy storage. The pair consisting of a high-temperature metal hydride (HTMH: Mg-based hydride) and a low-temperature metal hydride (LTMH: AB2 type hydride) is attractive due to its relatively high energy storage density and medium energy storage efficiency. The energy storage efficiency can be significantly increased by improving the heat discharging performance of the thermal battery. In this study, we experimentally explore the heat releasing performance of an MgH2/(TiZr)(MnFeCr)2-based thermal battery. More specifically, the effects of LTMH bed heat transfer conditions on the heat discharging performance were briefly discussed. These heat transfer conditions include natural convection, forced convection, and resistive heating. The results showed that when operating the LTMH bed under active heat transfer conditions (forced convection or resistive heating), the thermochemical energy storage density varies between 1500 and 1820 kJ/kg-Mg with relatively high-temperature lift (heat upgrade) between 47 and 55 °C. On the other side, the thermal battery discharges heat at a relatively high specific power, ca. 100–225 W/kg-Mg, which can be a benefit for heat-to-work conversion applications using organic or steam Rankine cycles.