Abstract

The heat capacity of deuterated cubic ammonium hexafluorosilicate (ND 4) 2SiF 6 was measured from 6 K to 343 K by adiabatic calorimetry. The curve of heat capacity against temperature is smooth and without anomalies. Values of the standard thermodynamic quantities are tabulated below 350 K. Analysis of our heat-capacity results yielded a librational wavenumber of the ND 4 + ion of about 122 cm −1 and a maximum in the rotational heat capacity lying between 220 K and 230 K.

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