Abstract

The high-temperature (HT) phase of Fe(C 5D 5) 2 is easily undercooled to exhibit a λ-type phase transition at 164.1 K in the metastable state. The stable low-temperature (LT) phase is obtained by annealing the undercooled HT phase around 190 K. A first-order phase transition characterized by a superheating effect occurs at 251 K between the stable LT and HT phases. A comparison with Fe(C 5H 5) 2 has been made.

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