Abstract
Low-temperature heat capacity C p,m of 2,6-dicarboxypyridine (C 7H 5NO 4; CAS 499-83-2) was precisely measured in the temperature range from (80 to 378) K with a high precision automated adiabatic calorimeter. No phase transition or thermal anomaly was observed in this range. The thermodynamic functions [ H T − H 298.15] and [ S T − S 298.15] were calculated in the range from (80 to 378) K. The standard molar enthalpy of combustion and the standard molar enthalpy of formation of the compound have been determined, Δ c H m ∘ ( C 7 H 5 NO 4 , cr ) = - ( 2741.41 ± 0.49 ) kJ · mol - 1 and Δ f H m ∘ ( C 7 H 5 NO 4 , cr ) = - ( 727.74 ± 1.50 ) kJ · mol - 1 , by means of a precision oxygen-bomb combustion calorimeter at T = 298.15 K. The thermodynamic properties of the compound were further investigated through differential scanning calorimeter (DSC) and the thermogravimetric (TG) analysis.
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