Heat capacity and density of solutions of calcium and cadmium nitrates in N-methylpyrrolidone at 298.15 K

Abstract

The heat capacity and density of solutions of calcium and cadmium nitrates in N-methylpyrrolidone (MP) at 298.15 K are studied by calorimetry and densimetry. The obtained data are discussed in relation to certain features of solvation and complex formation in solutions of these salts. The standard partial molar heat capacities and volumes (\(\overline {C_{p^2 }^0 }\) and \(\overline {V_2^0 }\)) of the electrolytes in MP are calculated. The standard heat capacities \(\overline {C_{p^i }^0 }\) and volumes \(\overline {V_i^0 }\) of Ca2+ and Cd2+ ions in MP at 298.15 K were determined, along with the contribution from specific interactions to the values of \(\overline {C_{p^i }^0 }\) and \(\overline {V_i^0 }\) of Cd2+ ions in MP solution.