Abstract
Measurements of heat capacities for liquid SbSe and BiSe alloys were carried out up to 800°C using an adiabatic scanning calorimeter. Anomalous temperature variation of heat capacity was observed for liquid Sb 0.45Se 0.55, Sb 0.5Se 0.5 and Bi 2Se 3 alloys. Broad maxima were observed in the temperature dependence of their heat capacities. In contrast, the heat capacity for liquid Sb 2Se 3 alloys shows little temperature variation. In the concentration dependence, the maximum of the heat capacity deviates from the stoichiometric composition of M 2Se 3 in both alloy systems. The characteristic behaviour of the heat capacities for liquid SbSe and BiSe alloys can be attributed to a change in intermediate-range order and in local bonding.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
