Abstract
Vapour phase He (II) photoelectron spectra of the thallium (I) and indium (I) halides MX (X = Cl, Br, I) are reported and compared with He (I) data. The additional structure in He (II) spectra is due largely to ionization of “inner”d electrons; the detail can be understood in terms of a weak-field perturbation of 2D5/2 and 2D final states associated with a d9 configuration at the metal ion. However, the spectrum of TICI contains certain extra features which probably represent many-electron (or shake-up) processes.
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Schedule a callMore From: Journal of the Chemical Society, Faraday Transactions 2
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