Abstract
A series of AlMCM-41 molecular sieves with different Si/Al ratios were synthesized followed by the deposition of cobalt and molybdenum oxides on these mesoporous supports by co-impregnation. Such materials were further calcined and catalysts with 15 wt.% of cobalt and molybdenum and a Co/(Co + Mo) atomic ratio of 0.30 were obtained. These materials were characterized by X-ray diffraction (XRD), transmission electron microscopy and selected area electron diffraction (TEM/SAED), X-ray fluorescence (XRF), and nitrogen adsorption. Hydrodesulphurisation (HDS) of thiophene was carried out at 350 °C in a fixed bed continuous flow micro reactor coupled on line to a gas chromatograph. The main XRD peaks of MCM-41 phase were observed in all samples and peaks due to MoO3 and CoMoO4 phases were also identified from XRD results. It was found that the as-synthesized catalysts presented reasonable conversion results for HDS of thiophene, when compared to other supported catalysts. The main products of HDS of thiophene were H2S, isobutene, 1-butene, n-butane, 2-butene-trans, and 2-butene-cis. It was observed that the reactivity of the as-synthesized catalysts is a direct function of the Si/Al ratio, nature and concentration of the active species on the mesoporous supports.
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