Hazardous gas emissions from the flanks of the quiescent Colli Albani volcano (Rome, Italy)

Abstract

Abstract Gas hazard was evaluated in the three most important cold gas emission zones on the flanks of the quiescent Colli Albani volcano. These zones are located above structural highs of the buried carbonate basement which represents the main regional aquifer and the main reservoir for gas rising from depth. All extensional faults affecting the limestone reservoir represent leaking pathways along which gas rises to the surface and locally accumulates in shallow permeable horizons forming pressurized pockets that may produce gas blowout when reached by wells. The gas, mainly composed of CO 2 (>90 vol.%), contains appreciable quantities of H 2 S (0.35–6 vol.%), and both represent a potentially high local hazard. Both gases are denser than air and accumulate near ground where they may reach hazardous concentrations, and lethal accidents frequently occur to animals watering at local ponds. In order to evaluate the rate of degassing and the related hazard, CO 2 and H 2 S diffuse soil flux surveys have been repeatedly carried out using an accumulation chamber. The viscous gas flux of some important discrete emissions has been evaluated and the CO 2 and H 2 S air concentration measured by portable devices and by Tunable Diode Laser profiles. The minimum potential lethal concentration of the two gases (250 ppm for H 2 S and 8 vol.% for CO 2 ) is 320 times higher for CO 2 , whereas the CO 2 /H 2 S concentration ratio in the emitted natural gas is significantly lower (15–159). This explains why H 2 S reaches hazardous, even lethal, concentrations more frequently than CO 2 . A relevant hazard exists for both gases in the depressed zones (channels, excavations) particularly in the non-windy early hours of the day.