Abstract
Functionally graded cemented carbides (FGCCs) usually have a coarse-grained surface layer. In order to refine the grain size of WC and to improve the mechanical properties, VC and NbC as grain growth inhibitors, were added to WC–6Co FGCCs. The grain growth kinetics of WC was investigated, and both the room temperature and high temperature mechanical properties were tested. The results show that the additions of NbC and VC reduce the thickness of the gradient layer in FGCCs. The addition of VC reduces the thickness of the gradient layer by half, while that of NbC is less effective. The additions of NbC and VC refine the grain size by suppressing the adsorption/desorption processes of WC grains in Co phase during the pre-sintering and the carburizing processes, and VC is more effective than NbC. The addition of NbC increases the transverse rupture strength of FGCCs, because of the fine microstructure, and the solution strengthening in Co phase. Both the additions of NbC and VC increase the high temperature hardness of FGCCs due to improved oxidation resistance, more homogeneous and finer microstructures.
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