Abstract

AbstractBulk electronic structures of covalent‐chain antiferromagnets TlFeS2 and TlFeSe2 have been investigated by hard X‐ray photoemission spectroscopy (HAXPES) and band calculations based on the full‐potential linearized augmented plane wave method. Competition between localized and delocalized characters of Fe 3d electrons has been suggested by the slight discrepancies between valence‐band HAXPES spectra and calculated density of states, as well as Fe 2p spectra with a broad charge‐transfer satellite. It is assumed that this competition closely related to the crystallographic onedimensionality of these materials. (© 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.