Hard Magnetic Property Improvement of Sputter-Prepared FePd Films on Glass Substrates by Underlayering With Refractory Nb, Mo, and W Elements

Abstract

Magnetic properties and structure of sputter-prepared FePd thin films on the glass substrates by underlayering with refractory elements M (M = Nb, Mo, and W) have been studied. The structural analysis shows that FePd films have a (111) preferred orientation. All studied FePd films exhibit in-plane magnetic anisotropy. For single-layer FePd films, the coercivity ( $H_{c})$ and magnetic energy product [(BH) $_{\mathrm {max}}]$ are increased with annealing temperature ( $T_{a})$ and reached the maximum value of 1.3 kOe and 3.8 MGOe in the sample annealing at 600 °C. With the further increase of $T_{a}$ , magnetic properties drop rapidly. Dependence of magnetic hardening on $T_{a}$ can be explained by dominant solid reactions in different region of $T_{a}$ including ordering and grain growth. Interestingly, magnetic properties of L10-FePd are largely improved by underlayering with 5 nm-thick Nb, Mo, and W layers. Both the coercivity and energy product are significantly increased to 1.6 kOe and 4.9 MGOe for M = Nb, 2.5 kOe and 6.4 MGOe for M = Mo, and 3.3 kOe and 8.7 MGOe for M = W, respectively. Structural analysis suggests that this magnetic enhancement is related to both higher ordering degree and refined microstructure.