Abstract

Absolute rate constants were determined for the additions of 5 5 -X-substituted ArCCl (X=CF 3, Cl, H, CH 3, CH 3O) to tetramethylethylene, trimethylethylene, trans-pentene, and 1-hexene; good Hammett correlations were obtained with ϱ = +1.4 – 1.6.

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