Abstract
Corrections are provided to our previous treatment [Chem. Phys. 208 (1996) 177] of generalized Hamiltonian operators for the description of the non-adiabatic interaction of two potential-energy surfaces coupled by collections of both symmetric and antisymmetric vibrational modes that restore invariance to unitary transformation of the operators. The form of other important projection and dipole-moment operators are also provided. These Hamiltonians are appropriate to a wide range of problems ranging from vibronic coupling in small aromatic molecules to intervalence charge-transfer phenomena to the operation of the special-pair solar to electrical energy converter in natural photosynthesis.
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