Haloantimonate(III) complexes with halogen-substituted quinolinium cations: Structural features of non-covalent interactions in solid state

Irina A Shentseva,Nikita A Korobeynikov,Andrey N Usoltsev,Igor D Gorokh,Alexander S Novikov,Ilya V Korolkov,Maxim N Sokolov,Sergey A Adonin

doi:10.1016/j.poly.2023.116505

Haloantimonate(III) complexes with halogen-substituted quinolinium cations: Structural features of non-covalent interactions in solid state

Irina A Shentseva, Nikita A Korobeynikov + Show 6 more

https://doi.org/10.1016/j.poly.2023.116505

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Journal: Journal of Inorganic and Nuclear Chemistry

Publication Date: Jun 20, 2023

Affiliation: Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, St Petersburg University, Russian New University, Peoples' Friendship University of Russia, A.E. Favorsky Irkutsk Institute of Chemistry

#Analysis Of Non-covalent Interactions #Interactions In Solid State + Show 8 more

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Abstract

Reactions between the halometalate-containing solutions (Sb2O3 in HCl or HBr) and halide salts of halogen-substituted quinolinium cations resulted in a series of haloantimonate complexes: (3-BrQuinH)4[Sb2X10] (X = Cl (1), Br (2)), (5-BrQuinH)2{[SbBr5]} (3), (1-Me-3-BrQuin)2[Sb2Cl8] (4) and (1-Me-3-BrQuin)3[Sb3Br12] (5). Their structures were determined using X-ray diffractometry; analysis of non-covalent interactions in crystalline state was performed by theoretical methods.

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