Halloysite nanotubes@polydopamine reinforced polyacrylamide-gelatin hydrogels with NIR light triggered shape memory and self-healing capability

Abstract

In this study, the polyacrylamide-gelatin composite hydrogels reinforced by halloysite nanotubes@polydopamine (HNTs@PDA) with NIR triggered shape memory performance and self-healing capacity were prepared through in-situ free radical polymerization of acrylamide in the mixture of Laponite-RD, HNTs@PDA and gelatin. HNTs@PDA was firstly synthesized through oxidative polymerization of dopamine on the surfaces of HNTs. HNTs@PDA was characterized by transmission electron microscopy, scanning electron microscopy, Fourier-transform infrared spectroscopy, X-ray diffraction, thermogravimetric analysis, Zeta potential, particle size analysis, and X-ray photoelectron spectroscopy. The photothermal performance of HNTs@PDA was then determined and the results reveal that HNTs@PDA can be employed as a superior photothermal agent to prepare light responsive hydrogels. The structure, morphology, mechanical properties, NIR triggered shape memory performance and self-healing capacity of the composite hydrogels were studied. The modified nanotubes act as cross-linking agent of polyacrylamide to form a rigid network in the hydrogel matrix, which leads to a significant increase in the mechanical properties. Moreover, the NIR triggered shape recovery process of the hydrogel is quite rapid, for example, it is only 63 s for recovering 720° shape change for the hydrogel of HNTs@PDA 40. The maximum NIR triggered healing efficiency of the hydrogels can reach 76%. The HNTs@PDA reinforced hydrogels with superior mechanical properties, NIR triggered shape memory, and self-healing ability exhibit promising applications in biomedical materials and smart engineering materials.