Abstract

This paper reports facile preparation of half-sandwich trihydrido complexes of ruthenium based on the reactions of the readily available precursors [Cp(R 3P)Ru(NCCH 3) 2][PF 6] with LiAlH 4. The target complexes were characterized by spectroscopic methods and X-ray structure analysis of Cp ( PhPr 2 i P ) RuH 3 .

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