Gum Arabic-based three-dimensional printed hydrogel for customizable sensors

Abstract

Most three-dimensional (3D) printed hydrogel exhibit non-idealized rheological properties in the process of direct ink writing and complicated curing. Therefore, accurate writability and convenient curing for 3D printed hydrogel remain a challenge. In this paper, we developed a typical 3D printed hydrogel which realized direct ink writing (DIW) at temperatures similar to human body. Silicon dioxide (SiO2) and Gum Arabic (GA) formed the Bingham fluid to ensure shape stability. The rapid initiation system of potassium persulfat (KPS) and N,N,N′,N′ -tetramethylethylenediamine (TMEDA) allowed the 3D printed hydrogel precursor solution to transiently form a hydrophobic conjoined cross-linking network structure of acrylamide (AAM) and lauryl methacrylate (LMA) after printing, resulting in preferable mechanical properties. Hydrogel precursor solution showed better rheological properties with the nature of Bingham fluids, and achieved transient cross-linking at 30 °C for 10 s in the rheological test. A variety of 3D printed hydrogel with individual strain sensing properties are prepared as customizable sensor that could monitor significant strain signals within 0–20 % strain with high sensitivity. Moreover, they were discovered excellent temperature sensitivity over a wide operating range (0–80 °C). The 3D printing hydrogel sensors were expected to have broad application prospects in flexible wearable devices and medical monitoring.