Guest network co‐continuity in interpenetrating polymer networks: A diffusion study

Abstract

AbstractInterpenetrating networks have been prepared using poly(dimethylsiloxane) as the host network and polymethacrylic acid as the guest network, i.e. polymerised and crosslinked in the presence of the siloxane network. These networks were swollen to equilibrium in dilute aqueous potassium chloride solutions and used as membranes to separate a solution of potassium chloride from pure water. The concentration of potassium chloride either side of each membrane was monitored as a function of time by conductivity measurements. From these data, the diffusion coefficient of potassium chloride in the membranes was calculated as a function of polymethacrylic acid content for temperatures of 303, 318 and 333K. Values of the diffusion coefficient were between 3 x 10−7cm2s−1 and 19 x 10−5 cm2 s−1. The activation energy of the diffusive process decreased linearly with the increase in water content of the networks.