Abstract

The design of modern semiconductor devices often requires the fabrication of three-dimensional (3D) structures to integrate microelectronic components with photonic, micromechanical, or sensor systems within one semiconductor substrate. It is a technologically challenging task, as a strictly defined profile of the device structure is obligatory. This can be achieved either by chemical etching or selective deposition on a masked substrate. In this paper, the growth uniformity of AlGaN/GaN heterostructures during selective-area metalorganic vapour-phase epitaxy (SA-MOVPE) was studied. Such structures are typically used in order to fabricate high-electron-mobility transistors (HEMT). The semiconductor material was deposited through 200 μm long stripe-shaped open windows in a SiO2 mask on GaN/sapphire templates. The window width was varied from 5 μm to 160 μm, whereas mask width separating particular windows varied from 5 μm to 40 μm. The experiment was repeated for three samples differing in GaN layer thickness: 150 nm, 250 nm, and 500 nm. Based on theoretical models of the selective growth, a sufficiently uniform thickness of epitaxially grown AlGaN/GaN heterostructure has been achieved by selecting the window half-width that is smaller than the diffusion length of the precursor molecules. A Ga diffusion length of 15 μm was experimentally extracted by measuring the epitaxial material agglomeration in windows in the dielectric mask. Measurements were conducted while using optical profilometry.

Highlights

  • Group III nitrides, including (Al, In, Ga)N compounds, gained importance at the turn of the 20th and 21st centuries, especially in the field of optoelectronics and high power electronics

  • Gallium nitride is characterised by a wide band gap (3.4 eV) [1], high chemical and temperature stability [2] and large piezoelectric coefficients [3]

  • This paper presents a new method for the estimation of the precursor molecules diffusion length according to the relative height difference between the edge and center of the grown heterostructure

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Summary

Introduction

Group III nitrides, including (Al, In, Ga)N compounds, gained importance at the turn of the 20th and 21st centuries, especially in the field of optoelectronics and high power electronics. Gallium nitride is characterised by a wide band gap (3.4 eV) [1], high chemical and temperature stability [2] and large piezoelectric coefficients [3]. Its unique properties make it a material of choice for many advanced semiconductor devices, such as: high temperature devices, high electron mobility transistors (HEMT), microwave instruments, facet lasers, electroacoustic transducers and electromechanical resonators, field emitters or integrated optics devices. Those devices consist of 3D structures, such as U-shaped and V-shaped grooves, mesa structures, nanowire matrices or planar waveguides, which can be produced in two ways. It is possible to integrate many opto-electro-mechanical devices

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