Growth, spectral, thermal, laser damage threshold, microhardness, dielectric, linear and nonlinear optical properties of an organic single crystal: L-phenylalanine DL-mandelic acid

Abstract

Single crystals of L-phenylalanine dl-mandelic acid [C9H11NO2. C8H8O3], have been grown by the slow evaporation technique at room temperature using aqueous solution. The single crystal XRD study confirms monoclinic system for the grown crystal. The functional groups present in the grown crystal have been identified by FTIR and FT-Raman analyses. The optical absorption studies show that the crystal is transparent in the visible region with a lower cut-off wavelength of 257nm and the optical band gap energy Eg is determined to be 4.62eV. The Kurtz powder second harmonic generation was confirmed using Nd:YAG laser with fundamental wavelength of 1064nm. Further, the thermal studies confirmed no weight loss up to 150°C for the as-grown crystal. The photoluminescence spectrum exhibited three peaks (414nm, 519nm, 568nm) due to the donation of protons from carboxylic acid to amino group. Laser damage threshold value was found to be 4.98GW/cm2. The Vickers microhardness test was carried out on the grown crystals and there by Vickers hardness number (Hv), work hardening coefficient (n), yield strength (σy), stiffness constant C11 were evaluated. The dielectric behavior of the crystal has been determined in the frequency range 50Hz–5MHz at various temperatures.