Abstract

The microstructure and magnetic properties of Ge:Fe thin films grown by molecular-beam epitaxy have been studied by transmission electron microscopy and superconducting quantum interference device magnetometry. Films were deposited on GaAs(001) at substrate temperatures (TS) ranging from 70to400°C. Nanoparticles of ferromagnetic Fe3Ge2 form in a single-crystalline Ge matrix for TS⩾150°C. The evolution of magnetic order has been evaluated as the particle size increases from 2nm at TS=150°C to 15nm at 400°C. The ferromagnetic order of Ge:Fe nanocomposite thin films originates solely from ferromagnetic second-phase particles.

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