Growth of CQD/PPy on cotton cloth as a binder-free high-performance flexible electrode for symmetric supercapacitor

Abstract

Benefited from the continuous development of nanomaterials, wearable microelectronics with flexible and miniaturized features are booming, and smart textiles are attracting more attentions because of their superior flexibility and perfect safety. The combination of conductive polymers and flexible substrates has created a new field for flexible supercapacitors. Herein, cotton cloth (CC), which is commonly used in daily life, was selected as the flexible substrate and a layer of CQDs was uniformly grown on the CC fibers, and then pyrrole was directly grown on CC by in-situ polymerization under Fe3+ initiation to realize the tight bonding between the conductive polymer and the flexible substrate. The electrochemical properties of the composite electrode could be controlled by changing the amount of CQD. The obtained CC@CQD@PPy electrode has a high specific capacitance (C) of 537.9 F/g at 0.5 A/g. The assembled symmetric CC@CQD@PPy supercapacitor exhibits an excellent energy density (E) of 18.7 Wh/kg at a power density (P) of 125.0 W/kg, and a supreme cycling stability with a capacitance retention of 77.9 % after 10,000 cycles. In addition, the CC@CQD@PPy supercapacitor has excellent flexibility, with almost unchanged electrochemical performance under different bending angles, and the assembled all-solid-state supercapacitor has good electrochemical properties.