Abstract

Cerium-containing films have been grown via plasma electrolytic oxidation in aqueous electrolytes containing Ce(III) polyphosphate complexes and have been characterized by x-ray microanalysis and x-ray diffraction. The films are shown to contain crystalline monazite, CePO4. Under certain conditions, multilayer surface structures grow on titanium. Air annealing of titanium/film structures at 750°C leads to crystallization of NaTi2(PO4)3 and CeP5O14.

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