Growth of Carbon Dot-Decorated ZnO Nanorods on a Graphite-Coated Paper Substrate to Fabricate a Flexible and Self-Powered Schottky Diode for UV Detection.

Abstract

The fabrication of flexible as well as self-powered optoelectronic devices is a growing and challenging area of research. Some scientists have reported the fabrication of either flexible or self-powered photodetectors recently. However, most of the literature studies fail to report the fabrication of self-powered as well as flexible photodetectors. This study reports the fabrication of self-powered, carbon dot (CD)-enhanced, flexible ZnO/graphite heterojunction-based UV detector where cellulose paper has been used as the substrate. A detailed study on the crystallinity and the defects of the ZnO nanorods has been done with appropriate characterizations. The CD-enhanced ZnO/graphite heterojunction showed Schottky characteristics. The Schottky parameters such as the barrier height, ideality factor, and the series resistance have also been calculated using the Cheung-Cheung method. The observed values of barrier height, ideality factor, and the series resistance are 0.74 eV, 3.74, and 503 kΩ, respectively. The transient response at self-powered condition has been demonstrated. The response time and the recovery time at self-powered condition have also been calculated with the help of the transient response, and those values are ∼2 and ∼3.2 s, respectively. The responsivity and the specific detectivity of the fabricated UV detector have been calculated as 9.57 mA/W and 4.27×108 Jones, respectively, at 330 nm wavelength, which is quite comparable with literature-reported values, considering a self-powered photodetector.