Abstract
This paper reports the growth of an organometallic nonlinear optical (NLO) complex crystal, Cadmium mercury thiocyanate dimethyl-sulphoxide (CdHg(SCN) 4(H 6CP 2OS) 2, CMTD), which was grown from aqueous solution by a temperature lowering method. Its powder SHG intensity is higher than that of CMTC. The crystal size of CMTD can reach 25×23×15mm 3. The solubility curve, and solubility variation with pH value are also reported. The growth habits of crystals of CMTD grown under different conditions are discussed and the optimized condition for the growth CMTD using a temperature-lowering method from aqueous solution are also discussed.
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