Abstract
Non-linear optical Sodium acid Phthalate (NaAP) single crystals was grown by slow evaporation from aqueous solutions. Structural characterization was carried out using X-ray diffraction analysis confirms the formation of the crystals in orthorhombic system with a space group of B2ab having unit-cell dimensions a = 9.2597(7)Å; b = 26.261(2)Å; c = 6.7355(6)Å; α = 90°; β = 90°; and γ =90°; Z=8. The vibrational frequencies of various functional groups present in the crystals have been ascertained through Fourier transform infrared spectroscopic (FTIR) analysis. Non-linear optical investigations carried out for the grown bulk crystals shows that the present crystal can be used as a high-frequency harmonic generators. The obtained results were discussed in detail.
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