Abstract
We have investigated the initial growth process of $\ensuremath{\alpha}$-Sn films on the In-terminated InSb(111)A-$(2\ifmmode\times\else\texttimes\fi{}2)$ surface using low-energy electron diffraction (LEED) and high-resolution core-level photoelectron spectroscopy. Taking the LEED observation and the Sn coverage-dependent integrated intensities of the In $4d$, Sb $4d$, and Sn $4d$ core-level spectra into account, we conclude that the $\ensuremath{\alpha}$-Sn film grows epitaxially by a bilayer mode and that there is no interdiffusion of the substrate atoms as suggested in the literature. Furthermore, the coverage-dependent In $4d$ and Sn $4d$ core levels indicate that the In vacancy site of InSb(111)A-$(2\ifmmode\times\else\texttimes\fi{}2)$ surface is not the preferable Sn absorption site.
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