Growth and thermal stability of Ag or Au films on Nb(110).

Abstract

The growth and thermal stability of ultrathin (<50-A-thick) Ag and Au films on Nb(110) was investigated with use of photoemission spectroscopy and low-energy electron-diffraction (LEED) patterns. The LEED results show that Ag or Au forms a monolayer which is commensurate with the substrate, but also show that the structure of this overlayer reverts to a more close-packed structure after three monolayers (ML) have been deposited. Photoemission spectra show trends that suggest the evolution of the Ag or Au band structure with coverage and also show that a surface deposit of at least 2 ML of Ag or Au is required to observe valence-band states characteristic of the bulk metal. Further examination of the photoemission spectra suggests that the Ag or Au d-band states play only a small role in the chemical bonding that occurs between the noble metals and Nb(110), and this can be contrasted with the extensive d-band involvement in chemisorption bonds formed between Pd or Pt and Nb(110). Heating does not cause substantial change in the electric structure of 12.8-ML-thick Ag films and they thermally desorb from Nb when heated above 830 K. Similar Au films intermix with Nb to form a disordered surface phase when heated beyondmore » 750 K. Desorption or complete in-diffusion of Au occurs when the substrate is heated beyond 1100 K. Implications for the formation of strained surface layers and surface chemical properties of noble metals on Nb(110) are discussed.« less