Abstract

The Er-doped YAB (YAl3(BO3)4) is a potential self-frequency-doubling laser material. Single crystals were grown by the top-seeded flux method. The absorption spectra of the infrared Er3☎ transitions were monitored in YAB crystals in the 9–300 K temperature range by high-resolution Fourier transform spectroscopy. In the whole spectral range the energy levels and Stark components of 12 transitions were detectable. In this paper the two infrared transitions (from the 4I15/2 ground state to the 4I13/2 and 4I11/2 levels) were analyzed in detail. The low temperature absorption spectra of Er:YAB consist of sharp lines, the number of which corresponds to the theoretical predictions. This suggests that Er3☎ ions occupy one specific lattice site (yttrium positions) with negligible aggregation at the higher dopant concentrations investigated (i.e. 0.12 Fr atom/YAB mole).

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