Groundwater quality of Yemen volcanic terrain and their geological and geochemical controls

Abstract

One hundred thirty boreholes of volcanic aquifers in rural Yemen Highland Groundwaters (YHGs) were chemically investigated to assess the suitability of water for drinking. Focus is to identify inorganic constituents of significant risk to health that occur in groundwaters of this area. Results showed that a number of boreholes contain, apart from fluoride, levels of nitrate, some heavy metals, total dissolved solids, and sulfates that could pose a health risk for consumers. The lateral variations of major ions with depth varied within the same aquifer based on the dynamic equilibrium of groundwater and hydrogeological conditions. The main inorganic groundwater contaminant in volcanic YHG is fluoride which is attributed to groundwater lithology and water type. Fluoride appears high in Ca-poor groundwater and where cation exchanges of Ca for Na are dominant. High F concentration in YHG is an extension of East African fluoride-rich groundwater. Majority of tube wells show that Fe concentration exceeds WHO guideline many folds. Much of the iron and manganese in groundwaters are naturally occurring, since the source rocks are enriched in ferromagnesian minerals. NO3− and Cl− concentrations that have been detected in some wells may indicate sewage and/or agricultural runoff. Elevated concentration of chemical constituents in groundwater is a sign of groundwater degradation.