Ground triplet pyrimidine-4,6-diyl bis(tert-butyl nitroxide) as a paramagnetic building block for metal–organic frameworks

Abstract

We synthesized pyrimidine-4,6-diyl bis(tert-butyl nitroxide) (pmbNO), and characterized as a biradical by means of ESR spectroscopy. The zero-field splitting parameters were |D|/hc=2.52×10−2cm−1 and |E|/hc=2.34×10−3cm−1 in frozen toluene at 100K. Magnetic study clarified the presence of intramolecular ferromagnetic coupling with 2J/kB=+18.5(5)K in frozen toluene–ethanol. DFT calculation supports the ground triplet state of pmbNO. The reaction of pmbNO with Cu(hfac)2 gave [Cu3(pmbNO)2(hfac)4], and the structure was determined by X-ray crystallographic analysis. Though the ligand was reduced to be an anion radical, pmbNO is confirmed to work as a rigid bridge, and the nitroxide oxygen atoms can ligate the metal ions.