Ground state C 2 density measurement in carbon plume using laser-induced fluorescence spectroscopy

Abstract

The temporal evolution and spatial distribution of C 2 molecules produced by laser ablation of a graphite target is studied using optical emission spectroscopy, dynamic imaging and laser-induced fluorescence (LIF) investigations. We observe peculiar bifurcation of carbon plume into two parts; stationary component close to the target surface and a component moving away from the target surface which splits further in two parts as the plume expands. The two distinct plumes are attributed to recombination of carbon species and formation of nanoparticles. The molecular carbon C 2 moves with a faster velocity and dies out at ~ 800 ns whereas the clusters of nanoparticle move with a slower velocity due to their higher mass and can be observed even after 1600 ns. C 2 molecules in the d 3Π g state were probed for laser-induced fluorescence during ablation of graphite using the Swan (0,0) band at 516.5 nm. The fluorescence spectrum and images of fluorescence d 3Π g − a 3Π u(0,1)( λ = 563.5 nm) are recorded using a spectrograph attached to the ICCD camera. To get absolute ground state C 2 density from fluorescence images, the images are calibrated using complimentary absorption experiment. This study qualitatively helps to get optimum conditions for nanoparticle formation using the laser ablation of graphite target and hence deducing optimum conditions for thin film deposition.