Ground-based and AIRS carbon monoxide behavior at El Arenosillo observatory (Southwestern Europe)

Abstract

Carbon monoxide (CO) observations registered at El Arenosillo observatory (Southwestern Europe), during three years (2019–2022) were used to explore levels, temporal variations and patterns. The seasonal mean hourly oscillated between 127 ± 21 and 97 ± 14 ppb, with extreme peaks measured under wildfire plume arrival. A remarkable monthly evolution was observed with peaks in cold months (135 ± 20 ppb in January) and minimum in summer (90 ± 11 ppb in June). Seasonal daily patterns showed a different nocturnal behavior depending on the season, with a clear maximum at 7:00–9:00 UTC, a decrease during diurnal time, and a minimum at 17:00–18:00 UTC. To determine the potential trends from 2002 to 2022, the observations of the AIRS (Atmospheric Infrared Sounder) instrument and the emissions from the global emission inventory of CAMS (Copernicus Atmosphere Monitoring Service) were used. A downward trend for emissions of −31% decade−1 was found, whereas the decrease from AIRS was −9.8% decade−1. The effort to reduce CO emissions is being countered by other processes. The CO behavior was investigated under weather conditions governed by the synoptic and mesoscale processes. Background levels (∼90 ppb) were obtained under Atlantic airflows, while an increase of ∼40% was observed with the impact of urban plumes from continental areas. CO even lower than 90 ppb was obtained under non-pure sea-land breezes, whereas, with pure breezes, reached peaks above 120 ppb, affecting the atmosphere at the surface and up to 1–1.2 km in the air. The extreme level was registered under wildfire plume arrival, with peaks exceeding 350 ppb. Climate change is modifying weather patterns and modulating breezes; in addition, it is also increasing the frequency and intensity of wildfires. These processes could be counteracting the efforts carried out to reduce emissions.