Abstract
The novel synthetic strategy for dolabellane skeleton was realized, which allowed the synthesis of clavulactone analogues 26 and 27 in a concise and efficient manner. Salient transformations include a diastereoselective Mukaiyama aldol reaction, an intramolecular nucleophilic addition reaction, a Grob fragmentation reaction, and an efficient Mukaiyama-Michael addition reaction.
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