Abstract
AbstractThe Green's function analysis of substituted and perturbed molecules is applied to the study of the vibrations of dibromogermane. The isotopic rules for the perturbation GeH2Br2 → GeD2Br2 are formulated and solved to arrive at the mixing parameter for each species of this molecule. The potential energy constants, mean amplitudes of vibration and Coriolis coupling constants are computed and compared with available literature values.
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