Green synthesis of Co-doped ZnO via the accumulation of cobalt ion onto Eichhornia crassipes plant tissue and the photocatalytic degradation efficiency under visible light

Abstract

Nowadays, water pollution is a major concern to the globe. For this reason, various research works has been done to access pure water thereby minimizing the effect of pollutants. In this work, the cobalt doped ZnO (Co-doped ZnO) via the accumulation of cobalt ion onto Eichhornia crassipes plant tissue for different days and combined with zinc precursor was synthesized. The resulting catalyst powder samples were characterized by Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), X-Ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FE-SEM), and Ultraviolet–vis (UV–vis) spectroscopy, and microwave plasma atomic emission spectrometer (MP-AES). The catalysts were also tested for the photocatalytic degradation of methylene blue (MB) in the presence of H2O2 under visible light irradiation. The best catalytic activity was gained by the 8th-days accumulation of cobalt ion onto the Eichhornia crassipes plant tissue and 99.6% of the dye was degraded within 45 min. However, 69.6, 65.7, 73.6, and 94.8% of MB dye was degraded by 1, 2, 4, and 6 days accumulations. Hence, removal of toxic heavy metal by using Eichhornia crassipes plant and recycling in the wastewater treatment gain is highly appreciated. Moreover, the Co-doped ZnO photocatalysts could enhance the photocatalytic activities due to suppressing of the electron and hole recombination and the porosity of the catalysts resulted from the Eichhornia crassipes plant after calcination.