Green Synthesis, Characterization, and Evaluation of Photocatalytic and Antibacterial Activities of Co3O4-ZnO Nanocomposites Using Calpurnia aurea Leaf Extract.

Abstract

The green synthesis of transition metal oxide nanocomposites using plant extracts is a new and effective method that avoids the involvement of hazardous chemicals. Nondegradable organic pollutants and antibiotic drug resistance have become serious public health issues worldwide. Hence, the main objective of this study is to synthesize Co3O4-ZnO nanocomposites using Calpurnia aurea leaf extract and evaluate its photocatalytic and antibacterial activities. The green synthesized particles were characterized using UV-vis spectra, Fourier transform infrared spectroscopy, X-ray diffraction techniques, and scanning electron microscopy combined with energy-dispersive X-ray studies. The synthesized particles were found to be crystalline in nature with average crystallite sizes of 23.82, 14.79, 15.99, 16.46, and 21.73 nm. Scanning electron microscopy shows the spherical morphology of Co3O4-ZnO NCs, and energy-dispersive X-ray analysis confirms the formation of highly pure ZnO NPs and Co3O4-ZnO NCs. The photocatalytic activity was performed under natural sunlight using malachite green as an organic dye pollutant. The green synthesized ZnO NPs, Co3O4 NPs, 1:4, 1:3, and 1:2 Co3O4-ZnO NCs showed high degradation efficiency after 60 min of irradiation. The synthetic material showed good potential against Staphylococcus aureus and Escherichia coli, with the highest growth inhibition recorded by 1:2 Co3O4-ZnO NCs. The kinetics study of the photocatalytic degradation was confirmed as pseudo first order, and the possible mechanisms for both photocatalytic and antibacterial activities were clearly determined.