Green conversion of waste PET into magnetic Ni0·4Fe2·6O4/(Fe,Ni)@carbon nanostructure for adsorption and separation of dyes from aqueous media

Abstract

A nanostructured core-shell composite (Ni0·4Fe2·6O4/(Fe,Ni)@carbon, NFC) comprising magnetic nano-cores encapsulated with graphitic shells (≈80 wt%) is prepared by facile and clean mechanochemical-molten salt processing approach using waste PET; providing a specific surface area of 201.9 m2 g−1, well-developed mesopores, and ferromagnetic behavior characterized by the coercivity value of 149 Oe. NFC is utilized as a high-performance adsorbent for the removal of organic dyes from their aqueous solutions. Moreover, the magnetic performance of NFC enables the facile collection of the exhausted adsorbent out of the purified water. Performances of NFC for the removal of crystal violet dye (CV), methyl orange (MO) and rhodamine B (Rh B) from their aqueous solutions are systematically investigated under different environmental conditions including the adsorbent dosage and dye concentration, as well as the solution pH and temperature, where an impressive CV removal capacity of 201.6–243.8 mg g−1 is recorded for a wide pH range of 2–10. Mechanism and kinetics involved in the adsorption process are investigated by studying the adsorption isotherms and thermodynamics. The dye adsorption of the nanocomposite material is confirmed to follow the pseudo-second-order kinetic model combined with the Langmuir isotherm model, exhibiting an excellent spontaneous and exothermic monolayer adsorption capacity of around 153 mg g−1 (for MO) for the fresh adsorbent and around 89 mg g−1 after three adsorption-regeneration cycles.