Green and sustainable route for oxidative depolymerization of lignin: New platform for fine chemicals and fuels.

Abstract

Depolymerization of lignin biomass to its value-added chemicals and fuels is pivotal for achieving the goals for sustainable society, and therefore has acquired key interest among the researchers worldwide. A number of distinct approaches have evolved in literature for the deconstruction of lignin framework to its mixture of complex constituents in recent decades. Among the existing practices, special attention has been devoted for robust site selective chemical transformation in the complex structural frameworks of lignin. Despite the initial challenges over a period of time, oxidation and oxidative cleavage process of aromatic building blocks of lignin biomass toward the fine chemical synthesis and fuel generation has improved substantially. The development has improved in terms of cost effectiveness, milder reaction conditions, and purity of compound individuals. These aforementioned oxidative protocols mainly involve the breaking of C-C and C-O bonds of complex lignin frameworks. More precisely in the line with environmentally friendly greener approach, the catalytic oxidation/oxidative cleavage reactions have received wide spread interest for their mild and selective nature toward the lignin depolymerization. This mini-review aims to provide an overview of recent developments in the field of oxidative depolymerization of lignin under greener and environmentally benign conditions. Also, these oxidation protocols have been discussed in terms of scalability and recyclability as catalysts for different fields of applications.