Green and robust adsorption and recovery of Europium(III) with a mechanism using hybrid donor conjugate materials

Abstract

The hybrid donor chemical ligand of 5-tert-butyl-2-hydroxybenzaldehyde thiosemicarbazone (THTB) was prepared and then embedded onto inorganic porous silica as hybrid conjugate materials (HCM). The Europium (Eu(III)) ion was selected from the lanthanides (Ln(III)) series for green and robust adsorption and recovery based on the adsorption, complexation, and selectivity tendency from the standpoint of the pH-dependent factor. The chemical compound of THTB consisted of O-, N-, and S-donor atoms and was able to make stable complexation with Ln(III) ions in optimum conditions due to the open functionality of the HCM. A surface complexation with a good complexation fitting to the experimentally collected data was used to describe the adsorption mechanism. The Eu(III) ion adsorption performance was measured with batch equilibrium methods. The affecting experimental protocols including solution pH, contact time, initial Eu(III) ion concentration, foreign ions effect, and recovery were carried out and evaluated consistently. The Eu(III) ion adsorption by the HCM was at pH 5.0 and this pH was selected to avoid the precipitation problem to ensure the adsorption mechanism. The co-existing several metal ions were not interfered with Eu(III) ion adsorption by the HCM due to the high affinity between Eu(III) ion and the functional groups of HCM. The bonding mechanism suggested that O-, N-, and S-donor atoms of THTB were strongly coordinated to Eu(III) with 2:1 ratio complexation. The Langmuir adsorption isotherm model was plotted due to the HCM morphology and applied to validate the adsorption isotherms according to the homogeneous ordered frameworks. The Eu(III) ion adsorption capacity by the HCM was 176.31 mg/g as expected because of the high surface area of the HCM. The adsorbed Eu(III) ion was completely eluted from HCM with the eluent of 0.20 M HNO3 and simultaneously regenerated into its initial form without significant deterioration. This study could be of great applicative utility for Eu(III) ions from waste aqueous solutions as green technology.