Green and Facile Synthesis of Porous SiO2@C Adsorbents from Rice Husk: Preparation, Characterization, and Their Application in Removal of Reactive Red 120 in Aqueous Solution.

Abstract

In this work, a green, novel, fast, and facile approach for synthesizing a SiO2/C nanocomposite series from rice husk (RH) through quenching and grinding techniques has been reported along with its application for the adsorptive removal of Reactive Red 120 (RR120) dye from an aqueous solution. The effect of carbonization temperature on the textural and interfacial features of RH was confirmed by scanning electron microscopy (SEM), while the structure and elemental composition of the as-synthesized RH were investigated via XRD, Brunauer-Emmett-Teller (BET), FT-IR, Raman, and X-ray photoelectron spectroscopy (XPS). The RH had a high surface area (521.35 m2 g-1), large micropores, mesopores, and total pore volumes of 0.5059, 3.9931, and 5.2196 cm3 g-1, while SiO2 and C were the two major components. In the batch adsorption test, the effects of pH, contact time, adsorbent mass, temperature, and initial RR120 concentration were investigated. The maximum adsorption capacity was fitted by Langmuir, Freundlich, Temkin, Dubinin-Radushkevich (D-R), Hasley, Harkins-Jura, and BET isotherm models, and Langmuir was the best-fitted model. In addition, the pseudo-first-order, pseudo-second-order, intraparticle diffusion, and Elovich chemisorption models were used to explain the adsorption kinetics. Additionally, the values of Gibbs free energy, enthalpy, and entropy thermodynamics suggested that the RR120 adsorption phenomenon by RH8-3 was endothermic and spontaneous. The adsorption process was controlled by a physical mechanism, and the maximum adsorption capacity was found to be 151.52 mg g-1 at pH 2, with a contact time of 90 min, adsorbent amount of 0.03 g, and temperature of 313 K. The adopted technique may open up a new alternative route for the mass utilization of RH for the removal of dyes in water and wastewater and also for various practical applications.