Greatly improved energy storage density of SrO2–BaO2–Nb2O5–SiO2–Al2O3–B2O3 glass ceramics by various amount CeO2 doping

Abstract

Glass ceramic dielectric materials with high power density and high energy density have important application value in the miniaturization and integration of lightweight pulse power devices. In this work, SrO2–BaO2–Nb2O5–SiO2–Al2O3–B2O3 glass ceramics doped with various contents of CeO2 were prepared via high-temperature melting combined with temperature-controlled crystallization process. Results showed that CeO2 doping increased the content of Ba0.27Sr0.75Nb2O5.78 tungsten bronze phase precipitate from the glass matrix in glass ceramics (from 55.7% to 82.2%), thereby increasing dielectric constant of SrO2–BaO2–Nb2O5–SiO2–Al2O3–B2O3 glass ceramics (from 66.5 to 101.9). Besides that, CeO2-doped ceramics exhibited excellent temperature stability and low loss (below 0.015). The highest breakdown strength (1590 kV/cm) and energy density (12.88 J/cm3) were achieved in the ceramic with a CeO2 doping concentration of 3.0 mol.%, being 3.03 times higher than those in undoped glass ceramic. The increase in energy density of the ceramics was attributed to moderate CeO2 doping concentration that improved the crystallinity (from 83.8% to 89.8%) and reduced the interfacial activation energy of the glass ceramics.